RESEARCH ON THE DISPOSAL OF ACIDIC WASTEWATER FROM THE SEPARATION OF FATTY ACIDS FROM COTTON SOAPSTOCK IN THE OIL INDUSTRY

Authors

  • S.Kh. Shamuratov Urgench State University Institute of General and Inorganic Chemistry, Academy of Sciences of the Republic of Uzbekistan Institute of Bioorganic Chemistry, Academy of Sciences of the Republic of Uzbekistan Tashkent Institute of Chemical Technology
  • U.K. Alimov Urgench State University Institute of General and Inorganic Chemistry, Academy of Sciences of the Republic of Uzbekistan Institute of Bioorganic Chemistry, Academy of Sciences of the Republic of Uzbekistan Tashkent Institute of Chemical Technology
  • D.S. Sagdullaeva Urgench State University Institute of General and Inorganic Chemistry, Academy of Sciences of the Republic of Uzbekistan Institute of Bioorganic Chemistry, Academy of Sciences of the Republic of Uzbekistan Tashkent Institute of Chemical Technology
  • U.S. Baltaev Urgench State University Institute of General and Inorganic Chemistry, Academy of Sciences of the Republic of Uzbekistan Institute of Bioorganic Chemistry, Academy of Sciences of the Republic of Uzbekistan Tashkent Institute of Chemical Technology

Keywords:

soapstock, acid wastewater, coagulant, chemical oxygen demand, biochemical oxygen demand.

Abstract

When raw cottonseed is processed, the resulting crude oil is subjected to refining to precipitate free fatty acids. If from 1 ton of seeds 18% crude oil is obtained, and from the same oil 9% of the total soapstock is extracted. The process of converting soap stock into fatty acids is accompanied by copious amounts of acidic runoff. This article presents the results of a study of wastewater treatment for the production of crude fatty acids using the sulfuric acid method.The mineralized mass of phosphorites of the Central Kyzylkum was used as a neutralizing agent. After neutralization and separation of phosphorite sediment, the water was further purified with coagulants such as Al2(SO4)3, Fe2(SO4)3, FeCl3 and PAA. It was found that after the use of aluminum sulfate, the indicators observed a decrease in hardness from 9.91 to 8.83 mEq/l, turbidity from 4.3 to 3.4; COD from 280 to 86, and pH from 8.80 to 8.40, and on the other hand, an increase in the degree of purification from 86.12 to 89.03%. The optimal dose of coagulants can be considered 4 g/l.

References

https://www.trend.az/casia/uzbekistan/3471996.html

Базаров Г.Р., Абдурахимов С.А. Получение поверхностно-активных веществ на основе жирных кислот хлопкового соапстока // Еuropean research: innovation in science, education and technology: Тез. докл.-Лондон.,https://elibrary.ru/item.asp?id=43971348

Горелова О.М., Кравченко Н.И. Исследование возможности переработки жиросодержащих отходов производства растительных масел. Ползуновский вестник № 4 Т.1 2015. –С. 68-72.

Пояркова Т.Н., Шестаков А.С., Прокофьев Ю.И., Шаталов Г.В., Селеменев В.Ф. Изучение коллоидно-химических свойств латексов, синтезированных на основе мыл соапстока, очищенного различными органическими растворителями. Вестник ВГУ, Серия: Химия. Биология. Фармация, 2016, №4. –С.32-36.

Равшанов Д.А., Кадиров Ю.К. Получение жирных кислот и глицерина из хлопковых соапстоков. VII Международная научно-практическая конференция. Современные тенденции развития науки и производства. Том II. 5 декабря 2017 г. – С. 184-187.

Равшанов Д.А., Кадиров Ю.К. К вопросу технологии переработки хлопковых соапстоков. https://www.elibrary.ru/item.asp?id=36696970

Аноров Р.А., Абидова М.А. Изучение физико-химических свойств водорастворимых ПАВ полученных из жирных кислот хлопкового соапстока // Universum: Химия и биология: электрон. научн. журн. 2019. № 12(66). URL: http://7universum.com/ru/nature/archive/item/8418

Asilbekova, D.T., Gusakova, S.D., Nazarova, I.P. et al. Composition of cottonseed soapstock fats. Chem Nat Compd 24, 424–429 (1988). https://doi.org/10.1007/BF00598524

Pominski J., PACK F.C. The Destruction of Gossypol in Cottonseed Oil Soapstock by a Heat Treatment. The Journal of the American Oil Chemists’ Society. 34, 1957. РР.299-301.

Dowd M.K. Compositional Characterization of Cottonseed Soapstocks. JAOCS, Vol. 73, no. 10 (1996). рр.1287- 1295.

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Published

2023-10-30

How to Cite

Shamuratov, S., Alimov, U., Sagdullaeva, D., & Baltaev, U. (2023). RESEARCH ON THE DISPOSAL OF ACIDIC WASTEWATER FROM THE SEPARATION OF FATTY ACIDS FROM COTTON SOAPSTOCK IN THE OIL INDUSTRY. RESEARCH AND EDUCATION, 2(10), 21–29. Retrieved from https://researchedu.org/index.php/re/article/view/5142